AP Chemistry thermochemistry key terms

Essential AP Chemistry thermochemistry key terms and concepts for exam preparation.

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APchemistrygeneral_chemistry
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What is thermochemistry?

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The study of heat changes that accompany chemical reactions.

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Quiz(14 preguntas)

Pregunta 1 de 14

1. What happens during an exothermic reaction?

Términos en este set(22)

What is thermochemistry?

The study of heat changes that accompany chemical reactions.

Define enthalpy (H).

The total heat content of a system, often expressed in kJ.

True or false: Exothermic reactions absorb heat.

False, because exothermic reactions release heat.

Difference between exothermic and endothermic.

Exothermic releases heat; endothermic absorbs heat.

What is calorimetry?

The measurement of heat flow during chemical reactions.

Fill in the blank: ΔH is negative for _____ reactions.

exothermic

Define specific heat capacity.

The amount of heat required to raise 1 g of a substance by 1 °C.

What does the symbol q represent?

The amount of heat absorbed or released.

True or false: Enthalpy is independent of the pathway taken.

True, because enthalpy is a state function.

What is the heat of formation?

The change in enthalpy when one mole of a compound forms from elements.

Difference between heat and temperature.

Heat is energy transfer; temperature measures kinetic energy of particles.

What is Hess's Law?

The total enthalpy change is the sum of changes for individual steps.

Define standard enthalpy change.

Enthalpy change under standard conditions (1 atm, 25 °C).

Fill in the blank: The bomb calorimeter measures _____ reactions.

combustion

What is the relationship between ΔH and ΔE?

ΔH = ΔE + PΔV (at constant pressure).

True or false: Heat can be measured directly.

False, because we measure temperature changes to calculate heat.

Define bond enthalpy.

The energy required to break one mole of bonds in a gaseous state.

What is entropy (S)?

A measure of disorder or randomness in a system.

Fill in the blank: A spontaneous process increases _____ in the universe.

entropy

Define Gibbs free energy (G).

The energy in a system that can do work; ΔG = ΔH - TΔS.

What is a thermochemical equation?

A balanced chemical equation that includes the enthalpy change.

Difference between heat of reaction and heat of formation.

Heat of reaction is for any reaction; heat of formation is for forming compounds.

Preguntas en este set(14)

1. What happens during an exothermic reaction?

A.Heat is released
B.Heat is absorbed
C.Temperature decreases
D.Energy is lost

2. Which of the following is a state function?

A.Heat
B.Work
C.Enthalpy
D.Pathway

3. What does a positive ΔH indicate?

A.Exothermic reaction
B.Endothermic reaction
C.No change
D.Heat lost

4. Which process increases entropy?

A.Freezing water
B.Condensing steam
C.Dissolving salt
D.Compressing gas

5. Which is NOT a unit of enthalpy?

A.kJ
B.cal
C.J/g°C
D.kJ/mol

6. A reaction has ΔG < 0. What does this imply?

A.Reaction is spontaneous
B.Reaction is non-spontaneous
C.Equilibrium condition
D.Requires energy input

7. What is the role of a calorimeter?

A.To measure mass
B.To measure heat change
C.To measure pressure
D.To measure volume

8. What is the standard condition for enthalpy changes?

A.1 atm and 25 K
B.1 atm and 0 °C
C.1 atm and 25 °C
D.2 atm and 25 °C

9. Which is true about Hess's Law?

A.Only applies to solid phases
B.Total change is independent of pathway
C.Only applies to gas phases
D.Applies only to exothermic reactions

10. Define the heat of formation of an element.

A.Always zero
B.Always positive
C.Always negative
D.Dependent on temperature

11. What is the effect of temperature on specific heat capacity?

A.Always increases
B.Always decreases
C.Can vary
D.Remains constant

12. What does ΔE represent in thermodynamics?

A.Change in energy
B.Change in temperature
C.Change in pressure
D.Change in volume

13. What best describes an endothermic reaction?

A.Releases heat
B.Absorbs heat
C.No heat change
D.Stable temperature

14. What unit is typically used for heat energy?

A.Joules
B.Liters
C.Meters
D.Celsius

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