AP Chem galvanic vs electrolytic cells key terms

Key terms and concepts related to galvanic and electrolytic cells for AP Chemistry review, including definitions, functions, and examples.

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Galvanic cell function?

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Converts chemical energy to electrical energy by spontaneous reactions.

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Quiz(32 questions)

Question 1 of 32

1. What is the primary function of a galvanic cell?

Terms in this Study Set(32)

Cell Types(16)

Galvanic cell function?

Converts chemical energy to electrical energy by spontaneous reactions.

Electrolytic cell function?

Uses electrical energy to drive non-spontaneous chemical reactions.

True or False: Galvanic cells require an external power source.

False - They generate their own power.

True or False: Electrolytic cells produce spontaneous reactions.

False - They require an external energy source.

Electrodes in galvanic cells?

Anode (negative) and cathode (positive), where oxidation and reduction occur.

Electrodes in electrolytic cells?

Anode (positive) and cathode (negative), opposite of galvanic cells.

Fill in the blank: In galvanic cells, the anode is __________.

Negative.

Fill in the blank: In electrolytic cells, the cathode is __________.

Negative.

Comparison: Galvanic vs. electrolytic cell reactions.

- Galvanic: spontaneous - Electrolytic: non-spontaneous

Cause → Effect: Increasing temperature in galvanic cell?

Increases reaction rate, potentially increasing voltage output.

Example of galvanic cell?

Daniell cell: Zn and Cu in separate solutions.

Example of electrolytic cell?

Electrolysis of water: splits H₂O into H₂ and O₂.

Standard cell potential (E°) does what?

Indicates the voltage produced by galvanic cells, positive for spontaneous.

Signs of cell potential: Galvanic vs electrolytic?

- Galvanic: E° > 0 - Electrolytic: E° < 0

Which cell type is used in batteries?

Galvanic cells.

Which cell type is used for electroplating?

Electrolytic cells.

Key Concepts(16)

Galvanic cell: spontaneous or non-spontaneous?

Spontaneous. Galvanic cells convert chemical energy into electrical energy.

Electrolytic cell: direction of electron flow?

Electrons flow from the anode to the cathode, opposite to galvanic cells.

What does a salt bridge do?

Maintains charge balance by allowing ions to move between half-cells.

True or false: Electrolytic cells require an external power source.

True. They need an external source to drive the non-spontaneous reaction.

Galvanic cell components?

Anode, cathode, salt bridge, electrolyte solution.

Electrode reaction at the anode?

Oxidation occurs, losing electrons. Example: Zn → Zn²⁺ + 2e⁻.

What does standard cell potential (Eextcell\displaystyle E^ ext{cell}) indicate?

The voltage produced by a galvanic cell under standard conditions.

Cause → Effect: Increasing concentration of reactants?

Increases cell voltage, drives the reaction forward.

What is the role of the cathode in an electrolytic cell?

Reduction occurs here; ions gain electrons. Example: Cu²⁺ + 2e⁻ → Cu.

Comparison: Anode in galvanic vs electrolytic cell.

Galvanic: oxidation, spontaneous. Electrolytic: oxidation, non-spontaneous.

What happens to the anode during electrolysis?

The anode dissolves as it loses electrons in oxidation reactions.

What is Faraday's law of electrolysis?

The amount of substance produced is proportional to the electric charge passed.

Fill in the blank: In galvanic cells, the cathode is _____.

positive, since it attracts cations.

What influences cell potential (Eextcell\displaystyle E^ ext{cell})?

Concentration, temperature, and type of reactants affect cell potential.

True or false: Both cell types have a cathode.

True. Both galvanic and electrolytic cells have cathodes for reduction.

What is a common use of electrolytic cells?

Electroplating metals, such as copper plating on jewelry.

Questions in this Study Set(32)

1. What is the primary function of a galvanic cell?

A.Converts chemical energy to electrical energy
B.Uses electrical energy to drive reactions
C.Stores electrical energy for later use
D.Reacts with an external power source

2. Which type of cell converts chemical energy into electrical energy?

A.Galvanic cell
B.Electrolytic cell
C.Both
D.Neither

3. What is the primary function of an electrolytic cell?

A.Generates power from spontaneous reactions
B.Drives non-spontaneous reactions using electrical energy
C.Stores energy in chemical bonds
D.Produces heat as a byproduct of reactions

4. In which direction do electrons flow in a galvanic cell?

A.From cathode to anode
B.From anode to cathode
C.From salt bridge to electrode
D.No electron flow

5. True or False: Galvanic cells need an external power source to operate.

A.True
B.False
C.Only in some cases
D.Depends on the temperature

6. What is the purpose of the salt bridge in a galvanic cell?

A.To conduct electricity
B.To maintain charge balance
C.To store energy
D.To increase voltage

7. True or False: Electrolytic cells can produce spontaneous reactions without additional energy.

A.True
B.False
C.Only at high temperatures
D.Only with certain materials

8. True or False: Electrolytic cells operate spontaneously.

A.True
B.False
C.Depends on conditions
D.Not enough information

9. What type of electrode is found at the anode of a galvanic cell?

A.Negative
B.Positive
C.Neutral
D.Inert

10. Which of the following is NOT a component of a galvanic cell?

A.Anode
B.Cathode
C.Salt bridge
D.Power supply

11. What type of electrode is found at the cathode of an electrolytic cell?

A.Negative
B.Positive
C.Neutral
D.Inert

12. What occurs at the anode of a galvanic cell?

A.Reduction
B.Oxidation
C.Precipitation
D.Neutralization

13. Which statement correctly compares galvanic and electrolytic cells?

A.Galvanic: non-spontaneous; Electrolytic: spontaneous
B.Galvanic: spontaneous; Electrolytic: non-spontaneous
C.Both are always spontaneous
D.Both require external power sources

14. What does a positive standard cell potential (Eextcell\displaystyle E^{ ext{cell}}) indicate?

A.Non-spontaneous reaction
B.Spontaneous reaction
C.No reaction
D.Equilibrium

15. What happens to the voltage output of a galvanic cell if the temperature increases?

A.Decreases
B.Increases
C.Remains the same
D.Becomes zero

16. What happens to cell voltage if the concentration of reactants increases?

A.Decreases
B.Increases
C.Remains the same
D.Becomes zero

17. Which of the following is a common example of a galvanic cell?

A.Daniell cell
B.Electrolysis of saltwater
C.Battery charger
D.Alkaline battery charger

18. Which process occurs at the cathode of an electrolytic cell?

A.Oxidation
B.Reduction
C.Electrolysis
D.Evaporation

19. Which of the following is a typical example of an electrolytic cell?

A.Daniell cell
B.Electrolysis of water
C.Dry cell battery
D.Lead-acid battery

20. Which statement compares anode reactions in galvanic and electrolytic cells?

A.Both are spontaneous
B.Both involve reduction
C.Both are oxidation
D.Both are neutral

21. What does standard cell potential (E°) indicate for galvanic cells?

A.Amount of energy consumed
B.Voltage produced by spontaneous reactions
C.Temperature at which reactions occur
D.Electrode material used

22. What happens to the anode in electrolysis?

A.It gains mass
B.It dissolves
C.It remains unchanged
D.It becomes positive

23. In which type of cell is the standard cell potential (E°) typically greater than zero?

A.Galvanic cells
B.Electrolytic cells
C.Both types
D.Neither type

24. What does Faraday's law of electrolysis state?

A.Mass produced is independent of charge
B.Mass produced is proportional to charge
C.Charge is independent of mass
D.Charge is proportional to time

25. Which cell type is commonly used in batteries?

A.Galvanic cells
B.Electrolytic cells
C.Both types
D.None of the above

26. Fill in the blank: In galvanic cells, the cathode is _____.

A.Positive
B.Negative
C.Neutral
D.Variable

27. Which cell type is primarily used for electroplating?

A.Galvanic cells
B.Electrolytic cells
C.Both types
D.Neither type

28. Which of the following influences cell potential (Eextcell\displaystyle E^{ ext{cell}})?

A.Concentration of reactants
B.Temperature
C.Type of reactants
D.All of the above

29. Which of the following describes a galvanic cell's anode?

A.Oxidation occurs here
B.Reduction occurs here
C.Always positive
D.Requires external power

30. True or False: Both galvanic and electrolytic cells have a cathode.

A.True
B.False
C.Only galvanic
D.Only electrolytic

31. Which of the following describes an electrolytic cell's cathode?

A.Site of reduction
B.Always positive
C.Produces electrical energy
D.Requires no external energy

32. What is a common application of electrolytic cells?

A.Generating electricity
B.Electroplating metals
C.Fuel cells
D.Batteries

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